ABSORPTION SPECTRA IN FUSED SALTS

Infra-red Absorption Spectra of Pyrylium Salts

The infra-red absorption spectra of the unsubstituted pyrylium cation and of 25 di-, tri-, tetraand per&-substituted pyrylium salts (mostly perchlorates) with alkyl and/or phenyl groups are described. Assignments of IR bands are made in correlation with the spectrum of pyridine, and the variation of band position and intensity depending on substitution is discussed. Implications for the assignm...

Miscibility Gaps in Fused Salts

The two families of systems formed by silver halides with alkali Chromates and tungstates have been systematically investigated in order to bring into evidence possible demixing phenomena. It has been found that silver chloride demixes with lithium Chromate and tungstate and with sodium tungstate; silver bromide demixes with lithium and sodium Chromates and tungstates; silver iodide demixes wit...

Structure absorption spectra correlation in a series of 2,6-dimethyl-4-arylpyrylium salts.

A combined experimental and theoretical study of the absorption spectra of a group of closely related pyrylium perchlorates 1-11 are presented. Minor changes in the position of the substituents lead to drastic changes in the absorption spectra in this series of compounds. We have attempted to explain the observed changes using the x,y-band notation developed by Balaban and co-workers. Absorptio...

Electronic Spectra of Chevreul’s Salts

Bile salts and calcium absorption.

1. The study of the effect of bile salts on enhancing calcium absorption in the rachitic chick has been extended to bile salts not present in chick bile, e.g. glycine conjugates and bile alcohol sulphates. 2. Bile and bile salts cause an increase in calcium absorption from sparingly soluble calcium hydrogen phosphate when compared with a suspension of calcium hydrogen phosphate in saline. 3. If...